| Index | Napoleon | Ohio | National |
| Average Test Scores | 74% | 61% | 48% |
| Student/Teacher ratio | 16:1 | 17:1 | 16:1 |
| Total public schools | 5 | 3,650 | 79,221 |
| Total private schools | 3 | 1,000 | 24,874 |
| Total post-secondary schools | n/a | 393 | 7,963 |
| Index | Napoleon | Ohio | National |
| Completed 8th grade | 87.6% | 86.9% | 84.3% |
| Completed high school | 86.9% | 85.6% | 83.0% |
| Completed some college | 45.4% | 55.7% | 59.4% |
| Completed associate degree | 24.5% | 35.1% | 38.5% |
| Completed bachelors | 15.1% | 26.7% | 30.3% |
| Completed masters | 6.2% | 10.0% | 11.5% |
| Completed professional degree | 1.1% | 2.7% | 3.3% |
| Completed doctorate | 0.8% | 1.1% | 1.3% |
There are a total of 5 public schools, 3 private schools and n/a post-secondary schools in Napoleon. Using the proficiency score averages, the average test scores for Napoleon, OH schools is 74%. The average student to teacher ratio is 16:1. In Napoleon, OH, an average of 87.6% of students have completed 8th grade and an average of 86.9% have completed high school.
| City | Population | Avg. Test Scores | National Avg. |
| Archbold, OH | 4,379 | 82% | 70.5% |
| Pettisville, OH | 546 | 81% | 68.2% |
| Holgate, OH | 1,149 | 77% | 60.4% |
| Delta, OH | 2,838 | 76% | 57.6% |
| Liberty Center, OH | 1,051 | 76% | 57.6% |
| Napoleon, OH | 8,310 | 74% | 53.6% |
| City | Population | Avg. Test Scores | National Avg. |
| Millersville, PA | 8,309 | 74% | 54.7% |
| Hawthorn Woods, IL | 8,313 | 51% | 6.6% |
| Runnemede, NJ | 8,307 | 39% | 18.5% |
| Price, UT | 8,303 | 45% | 6.9% |
| Denison, IA | 8,319 | 63% | 31.3% |
| Napoleon, OH | 8,310 | 74% | 53.6% |
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