| Index | New Union | Alabama | National |
| Average Test Scores | n/a | 44% | 48% |
| Student/Teacher ratio | n/a | 15:1 | 16:1 |
| Total public schools | n/a | 1,307 | 79,221 |
| Total private schools | n/a | 353 | 24,874 |
| Total post-secondary schools | n/a | 102 | 7,963 |
| Index | New Union | Alabama | National |
| Completed 8th grade | 71.2% | 80.7% | 84.3% |
| Completed high school | 71.2% | 79.2% | 83.0% |
| Completed some college | 44.8% | 53.8% | 59.4% |
| Completed associate degree | 24.8% | 31.9% | 38.5% |
| Completed bachelors | 8.2% | 24.0% | 30.3% |
| Completed masters | 3.3% | 8.9% | 11.5% |
| Completed professional degree | 0.0% | 2.5% | 3.3% |
| Completed doctorate | 0.0% | 1.0% | 1.3% |
There are a total of n/a public schools, n/a private schools and n/a post-secondary schools in New Union. Using the proficiency score averages, the average test scores for New Union, AL schools is n/a. The average student to teacher ratio is n/a. In New Union, AL, an average of 71.2% of students have completed 8th grade and an average of 71.2% have completed high school.
| City | Population | Avg. Test Scores | National Avg. |
| Rainbow City, AL | 9,601 | 64% | 33.9% |
| Steele, AL | 1,133 | 62% | 29.2% |
| Southside, AL | 8,801 | 57% | 18.8% |
| Oneonta, AL | 6,550 | 55% | 14.8% |
| Boaz, AL | 9,587 | 47% | 2.8% |
| New Union, AL | 1,008 | n/a |
| City | Population | Avg. Test Scores | National Avg. |
| Knox, PA | 1,008 | 60% | 25.5% |
| Rice, TX | 1,008 | 39% | 18.2% |
| West Cape May, NJ | 1,008 | 60% | 25.0% |
| Savoy, TX | 1,007 | 53% | 10.9% |
| Franklin, GA | 1,007 | 56% | 17.4% |
| New Union, AL | 1,008 | n/a |
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