| Index | Pevely | Missouri | National |
| Average Test Scores | 47% | 44% | 48% |
| Student/Teacher ratio | 14:1 | 14:1 | 16:1 |
| Total public schools | 1 | 1,899 | 79,221 |
| Total private schools | n/a | 531 | 24,874 |
| Total post-secondary schools | n/a | 213 | 7,963 |
| Index | Pevely | Missouri | National |
| Completed 8th grade | 79.5% | 86.0% | 84.3% |
| Completed high school | 79.5% | 84.2% | 83.0% |
| Completed some college | 58.5% | 57.7% | 59.4% |
| Completed associate degree | 31.2% | 35.2% | 38.5% |
| Completed bachelors | 13.7% | 27.6% | 30.3% |
| Completed masters | 2.9% | 10.4% | 11.5% |
| Completed professional degree | 0.8% | 2.8% | 3.3% |
| Completed doctorate | 0.8% | 1.2% | 1.3% |
There are a total of 1 public schools, n/a private schools and n/a post-secondary schools in Pevely. Using the proficiency score averages, the average test scores for Pevely, MO schools is 47%. The average student to teacher ratio is 14:1. In Pevely, MO, an average of 79.5% of students have completed 8th grade and an average of 79.5% have completed high school.
| City | Population | Avg. Test Scores | National Avg. |
| Festus, MO | 12,054 | 59% | 23.1% |
| Eureka, MO | 10,203 | 59% | 22.7% |
| Waterloo, IL | 10,417 | 59% | 22.4% |
| Herculaneum, MO | 4,081 | 56% | 16.7% |
| Columbia, IL | 10,692 | 56% | 16.7% |
| Pevely, MO | 5,937 | 47% | 2.1% |
| City | Population | Avg. Test Scores | National Avg. |
| Portland, CT | 5,937 | 61% | 26.3% |
| Hilmar-Irwin, CA | 5,937 | 40% | 16.9% |
| Lake Mills, WI | 5,936 | 48% | 0.7% |
| Taylor, PA | 5,935 | 50% | 4.2% |
| Columbia, MS | 5,940 | 40% | 16.7% |
| Pevely, MO | 5,937 | 47% | 2.1% |
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