| Index | Purcellville | Virginia | National |
| Average Test Scores | 89% | 79% | 48% |
| Student/Teacher ratio | 14:1 | 13:1 | 16:1 |
| Total public schools | 6 | 1,596 | 79,221 |
| Total private schools | n/a | 553 | 24,874 |
| Total post-secondary schools | 1 | 199 | 7,963 |
| Index | Purcellville | Virginia | National |
| Completed 8th grade | 92.0% | 85.9% | 84.3% |
| Completed high school | 91.3% | 84.7% | 83.0% |
| Completed some college | 76.9% | 64.1% | 59.4% |
| Completed associate degree | 59.6% | 44.2% | 38.5% |
| Completed bachelors | 50.6% | 36.9% | 30.3% |
| Completed masters | 19.7% | 15.7% | 11.5% |
| Completed professional degree | 4.5% | 4.2% | 3.3% |
| Completed doctorate | 2.6% | 1.7% | 1.3% |
There are a total of 6 public schools, n/a private schools and 1 post-secondary schools in Purcellville. Using the proficiency score averages, the average test scores for Purcellville, VA schools is 89%. The average student to teacher ratio is 14:1. In Purcellville, VA, an average of 92.0% of students have completed 8th grade and an average of 91.3% have completed high school.
| City | Population | Avg. Test Scores | National Avg. |
| Round Hill, VA | 695 | 90% | 86.5% |
| Belmont, VA | 9,341 | 89% | 85.4% |
| Ashburn, VA | 44,090 | 88% | 84.1% |
| Stone Ridge, VA | 15,034 | 88% | 83.3% |
| Middleburg, VA | 573 | 87% | 81.3% |
| Purcellville, VA | 10,063 | 89% | 84.8% |
| City | Population | Avg. Test Scores | National Avg. |
| Cedartown, GA | 10,062 | 34% | 28.7% |
| Winterville, NC | 10,062 | 49% | 1.3% |
| Marina del Rey, CA | 10,065 | 39% | 18.8% |
| Bastrop, LA | 10,060 | 52% | 9.1% |
| Kennett, MO | 10,069 | 45% | 6.6% |
| Purcellville, VA | 10,063 | 89% | 84.8% |
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